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Phearman, Alexander S.; Moore, Jewelianna M.; Bhagwandin, Dayanni D.; Goldberg, Jonathan M.; Heinekey, D. Michael; Goldberg, Karen I. (, Green Chemistry)null (Ed.)The Aldehyde-Water Shift (AWS) reaction uses H 2 O as a benign oxidant to convert aldehydes to carboxylic acids, producing H 2 , a valuable reagent and fuel, as its sole byproduct. (Hexamethylbenzene)Ru II complexes are demonstrated to have higher activity and selectivity (up to 95%) for AWS over disproportionation than previously reported catalysts.more » « less
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Zhao, Chenxiao; Bhagwandin, Dayanni D.; Xu, Wangwei; Ruffieux, Pascal; Khan, Saeed I.; Pignedoli, Carlo A.; Fasel, Roman; Rubin, Yves (, Journal of the American Chemical Society)
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